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10.1073/pnas.1721503115

http://scihub22266oqcxt.onion/10.1073/pnas.1721503115
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C6042087!6042087!29891684
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suck abstract from ncbi


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pmid29891684      Proc+Natl+Acad+Sci+U+S+A 2018 ; 115 (26): 6566-71
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  • Electron?hole separation in ferroelectric oxides for efficient photovoltaic responses #MMPMID29891684
  • Kim D; Han H; Lee JH; Choi JW; Grossman JC; Jang HM; Kim D
  • Proc Natl Acad Sci U S A 2018[Jun]; 115 (26): 6566-71 PMID29891684show ga
  • Photovoltaics (PVs) benefitting from ferroelectric polarizations can overcome critical limitations of conventional type PVs. In this class, Bi2FeCrO6 is known to be the best-performing material; however, a fundamental understanding of the origin is lacking, which has limited further performance improvements. Here, we carried out a theoretical investigation of the electronic structure of this material. As a result, electron?hole (e-h) pairs are observed to separate upon photoexcitation, which can be a dominant underlying mechanism for the exceptional PV responses. Based on this understanding, we further suggest five novel materials that can offer a combination of strong e-h separations and visible-light absorptions. We expect the community of ferroelectric PVs to immediately benefit from the features of the new suggested materials.
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