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10.1039/c6sc01478j http://scihub22266oqcxt.onion/10.1039/c6sc01478j C6022229!6022229 !30034747     free     free     free Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=30034747 &cmd=llinks): Failed to open stream: HTTP request failed! 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Donor-?-donor type hole transporting materials: marked ?-bridge effects on optoelectronic properties, solid-state structure, and perovskite solar cell efficiency |pdf=|usr=}}{{30034747 }} gab.com Text Donor- -donor type hole transporting materials: marked -bridge effects on optoelectronic properties, solid-state structure, and perovskite solar cell efficiency JO: Chem Sci http://www.kidney.de/pget.php?&tw=1&pmid=30034747 #FOAvip Donor-?-bridge-donor type oligomers (D-?-D) have been studied intensively as active materials for organic optoelectronic devices. In this study, we introduce three new D-?-D type organic semiconductors incorporating thiophene or thienothiophene with two electron-rich TPA units, which can be easily synthesized from commercially available materials. A thorough comparison of their optoelectronic and structural properties was conducted, revealing the strong influence of the extent of longitudinal ?-bridge conjugation on both the solid structure of the organic semiconductive materials and their photovoltaic performance when applied as hole transporting materials (HTM) in perovskite solar cells. Single-crystal measurements and time-resolved photoluminescence (TRPL) studies indicate that these coplanar donor-?-donor type HTMs could be promising alternatives to state-of-the-art spiro-OMeTAD, due to the multiple intermolecular short contacts as charge transporting channels and efficient charge extraction properties from the perovskite layer. The optimized devices with PEH-9 exhibited an impressive PCE of 16.9% under standard global AM 1.5 illumination with minimized hysteretic behaviour, which is comparable to that of devices using spiro-OMeTAD under similar conditions. Ambient stability after 400 h revealed that 93% of the energy conversion efficiency was retained for PEH-9, indicating that the devices had good long-term stability. Twit Text FOAVip Donor- -donor type hole transporting materials: marked -bridge effects on optoelectronic properties, solid-state structure, and perovskite solar cell efficiency ????Chem Sci http://www.kidney.de/pget.php?&tw=1&pmid=30034747 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=30034747 #FOAvip English Wikipedia <ref>{{Cite pmid|30034747 }}</ref> Donor-?-donor type hole transporting materials: marked ?-bridge effects on optoelectronic properties, solid-state structure, and perovskite solar cell efficiency #MMPMID30034747 Paek S ; Zimmermann I ; Gao P ; Gratia P ; Rakstys K ; Grancini G ; Nazeeruddin MK ; Rub MA ; Kosa SA ; Alamry KA ; Asiri AM Chem Sci 2016[Sep]; 7 (9 ): 6068-6075 PMID30034747 show ga Donor-?-bridge-donor type oligomers (D-?-D) have been studied intensively as active materials for organic optoelectronic devices. In this study, we introduce three new D-?-D type organic semiconductors incorporating thiophene or thienothiophene with two electron-rich TPA units, which can be easily synthesized from commercially available materials. A thorough comparison of their optoelectronic and structural properties was conducted, revealing the strong influence of the extent of longitudinal ?-bridge conjugation on both the solid structure of the organic semiconductive materials and their photovoltaic performance when applied as hole transporting materials (HTM) in perovskite solar cells. Single-crystal measurements and time-resolved photoluminescence (TRPL) studies indicate that these coplanar donor-?-donor type HTMs could be promising alternatives to state-of-the-art spiro-OMeTAD, due to the multiple intermolecular short contacts as charge transporting channels and efficient charge extraction properties from the perovskite layer. The optimized devices with PEH-9 exhibited an impressive PCE of 16.9% under standard global AM 1.5 illumination with minimized hysteretic behaviour, which is comparable to that of devices using spiro-OMeTAD under similar conditions. Ambient stability after 400 h revealed that 93% of the energy conversion efficiency was retained for PEH-9, indicating that the devices had good long-term stability. äDonor-?-donor type hole transporting materials: marked ?-bridge effect(epmc).pdf DeepDyve Pubget Overpricing