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10.1038/s41598-018-27901-4

http://scihub22266oqcxt.onion/10.1038/s41598-018-27901-4
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C6014996!6014996!29934509
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suck abstract from ncbi


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pmid29934509      Sci+Rep 2018 ; 8 (ä): ä
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  • Cooperative bi-exponential decay of dye emission coupled via plasmons #MMPMID29934509
  • Lyvers DP; Moazzezi M; de Silva VC; Brown DP; Urbas AM; Rostovtsev YV; Drachev VP
  • Sci Rep 2018[]; 8 (ä): ä PMID29934509show ga
  • Bi-exponential decay of dye fluorescence near the surface of plasmonic metamaterials and core-shell nanoparticles is shown to be an intrinsic property of the coupled system. Indeed, the Dicke, cooperative states involve two groups of transitions: super-radiant, from the most excited to the ground states and sub-radiant, which cannot reach the ground state. The relaxation in the sub-radiant system occurs mainly due to the interaction with the plasmon modes. Our theory shows that the relaxation leads to the population of the sub-radiant states by dephasing the super-radiant Dicke states giving rise to the bi-exponential decay in agreement with the experiments. We use a set of metamaterial samples consisting of gratings of paired silver nanostrips coated with Rh800 dye molecules, having resonances in the same spectral range. The bi-exponential decay is demonstrated for Au\SiO2\ATTO655 core-shell nanoparticles as well, which persists even when averaging over a broad range of the coupling parameter.
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