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10.1038/s41467-018-04263-z http://scihub22266oqcxt.onion/10.1038/s41467-018-04263-z C5964112!5964112 !29789602     free     free     free Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=29789602 &cmd=llinks): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 215       Nat+Commun 2018 ; 9 (1 ): 1890 Nephropedia Template TP {{tp|p=29789602 |t=2018. Hygroscopic compounds in spider aggregate glue remove interfacial water to maintain adhesion in humid conditions |pdf=|usr=}}{{29789602 }} gab.com Text Hygroscopic compounds in spider aggregate glue remove interfacial water to maintain adhesion in humid conditions JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=29789602 #FOAvip Adhesion in humid environments is fundamentally challenging because of the presence of interfacial bound water. Spiders often hunt in wet habitats and overcome this challenge using sticky aggregate glue droplets whose adhesion is resistant to interfacial failure under humid conditions. The mechanism by which spider aggregate glue avoids interfacial failure in humid environments is still unknown. Here, we investigate the mechanism of aggregate glue adhesion by using interface-sensitive spectroscopy in conjunction with infrared spectroscopy. We demonstrate that glycoproteins act as primary binding agents at the interface. As humidity increases, we observe reversible changes in the interfacial secondary structure of glycoproteins. Surprisingly, we do not observe liquid-like water at the interface, even though liquid-like water increases inside the bulk with increasing humidity. We hypothesize that the hygroscopic compounds in aggregate glue sequester interfacial water. Using hygroscopic compounds to sequester interfacial water provides a novel design principle for developing water-resistant synthetic adhesives. Twit Text FOAVip Hygroscopic compounds in spider aggregate glue remove interfacial water to maintain adhesion in humid conditions ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=29789602 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=29789602 #FOAvip English Wikipedia <ref>{{Cite pmid|29789602 }}</ref> Hygroscopic compounds in spider aggregate glue remove interfacial water to maintain adhesion in humid conditions #MMPMID29789602 Singla S ; Amarpuri G ; Dhopatkar N ; Blackledge TA ; Dhinojwala A Nat Commun 2018[May]; 9 (1 ): 1890 PMID29789602 show ga Adhesion in humid environments is fundamentally challenging because of the presence of interfacial bound water. Spiders often hunt in wet habitats and overcome this challenge using sticky aggregate glue droplets whose adhesion is resistant to interfacial failure under humid conditions. The mechanism by which spider aggregate glue avoids interfacial failure in humid environments is still unknown. Here, we investigate the mechanism of aggregate glue adhesion by using interface-sensitive spectroscopy in conjunction with infrared spectroscopy. We demonstrate that glycoproteins act as primary binding agents at the interface. As humidity increases, we observe reversible changes in the interfacial secondary structure of glycoproteins. Surprisingly, we do not observe liquid-like water at the interface, even though liquid-like water increases inside the bulk with increasing humidity. We hypothesize that the hygroscopic compounds in aggregate glue sequester interfacial water. Using hygroscopic compounds to sequester interfacial water provides a novel design principle for developing water-resistant synthetic adhesives. ?Hygroscopic compounds in spider aggregate glue remove interfacial wate(epmc).pdf DeepDyve Pubget Overpricing