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10.1038/s41467-018-04335-0

http://scihub22266oqcxt.onion/10.1038/s41467-018-04335-0
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C5958055!5958055!29773784
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suck abstract from ncbi


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pmid29773784      Nat+Commun 2018 ; 9 (ä): ä
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  • Coulombic-enhanced hetero radical pairing interactions #MMPMID29773784
  • Zheng X; Zhang Y; Cao N; Li X; Zhang S; Du R; Wang H; Ye Z; Wang Y; Cao F; Li H; Hong X; Sue ACH; Yang C; Liu WG; Li H
  • Nat Commun 2018[]; 9 (ä): ä PMID29773784show ga
  • Spin?spin interactions between two identical aromatic radicals have been studied extensively and utilized to establish supramolecular recognition. Here we report that spin-pairing interactions could also take place between two different ?-electron radicals, namely a bipyridinium radical cation (BPY+?) and a naphthalene-1,8:4,5-bis(dicarboximide) radical anion (NDI??). The occurrence of this type of previously unreported hetero radical-pairing interactions is attributed to enhancement effect of Coulombic attraction between these two radicals bearing opposite charges. The Coulombic-enhanced hetero radical pairing interactions are employed to drive host?guest recognition, as well as the reversible switching of a bistable [2]rotaxane.
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