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10.1038/s41467-018-04228-2 http://scihub22266oqcxt.onion/10.1038/s41467-018-04228-2 C5951818!5951818!29760476     free     free     free       Nat+Commun 2018 ; 9 (ä): ä Nephropedia Template TP {{tp|p=29760476|t=2018. Self-organizing layers from complex molecular anions |pdf=|usr=}}{{29760476}} gab.com Text Self-organizing layers from complex molecular anions JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=29760476 #FOAvip The formation of traditional ionic materials occurs principally via joint accumulation of both anions and cations. Herein, we describe a previously unreported phenomenon by which macroscopic liquid-like thin layers with tunable self-organization properties form through accumulation of stable complex ions of one polarity on surfaces. Using a series of highly stable molecular anions we demonstrate a strong influence of the internal charge distribution of the molecular ions, which is usually shielded by counterions, on the properties of the layers. Detailed characterization reveals that the intrinsically unstable layers of anions on surfaces are stabilized by simultaneous accumulation of neutral molecules from the background environment. Different phases, self-organization mechanisms and optical properties are observed depending on the molecular properties of the deposited anions, the underlying surface and the coadsorbed neutral molecules. This demonstrates rational control of the macroscopic properties (morphology and size of the formed structures) of the newly discovered anion-based layers. Twit Text FOAVip Self-organizing layers from complex molecular anions ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=29760476 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=29760476 #FOAvip English Wikipedia <ref>{{Cite pmid|29760476}}</ref> Self-organizing layers from complex molecular anions #MMPMID29760476 Warneke J; McBriarty ME; Riechers SL; China S; Engelhard MH; Aprą E; Young RP; Washton NM; Jenne C; Johnson GE; Laskin J Nat Commun 2018[]; 9 (ä): ä PMID29760476show ga The formation of traditional ionic materials occurs principally via joint accumulation of both anions and cations. Herein, we describe a previously unreported phenomenon by which macroscopic liquid-like thin layers with tunable self-organization properties form through accumulation of stable complex ions of one polarity on surfaces. Using a series of highly stable molecular anions we demonstrate a strong influence of the internal charge distribution of the molecular ions, which is usually shielded by counterions, on the properties of the layers. Detailed characterization reveals that the intrinsically unstable layers of anions on surfaces are stabilized by simultaneous accumulation of neutral molecules from the background environment. Different phases, self-organization mechanisms and optical properties are observed depending on the molecular properties of the deposited anions, the underlying surface and the coadsorbed neutral molecules. This demonstrates rational control of the macroscopic properties (morphology and size of the formed structures) of the newly discovered anion-based layers. äSelf-organizing layers from complex molecular anions (epmc).pdf DeepDyve Pubget Overpricing