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10.1002/anie.201801452 http://scihub22266oqcxt.onion/10.1002/anie.201801452 C5947745!5947745!29558562     free     free     free Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Angew+Chem+Int+Ed+Engl 2018 ; 57 (19): 5408-12 Nephropedia Template TP {{tp|p=29558562|t=2018. Catalysis with Pnictogen, Chalcogen, and Halogen Bonds |pdf=|usr=}}{{29558562}} gab.com Text Catalysis with Pnictogen, Chalcogen, and Halogen Bonds JO: Angew Chem Int Ed Engl http://www.kidney.de/pget.php?&tw=1&pmid=29558562 #FOAvip Halogen? and chalcogen?based ??hole interactions have recently received increased interest in non?covalent organocatalysis. However, the closely related pnictogen bonds have been neglected. In this study, we introduce conceptually simple, neutral, and monodentate pnictogen?bonding catalysts. Solution and in?silico binding studies, together with high catalytic activity in chloride abstraction reactions, yield compelling evidence for operational pnictogen bonds. The depth of the ??holes is easily varied with different substituents. Comparison with homologous halogen? and chalcogen?bonding catalysts shows an increase in activity from main group?VII to V and from row?3 to 5 in the periodic table. Pnictogen bonds from antimony thus emerged as by far the best among the elements covered, a finding that provides most intriguing perspectives for future applications in catalysis and beyond. Twit Text FOAVip Catalysis with Pnictogen, Chalcogen, and Halogen Bonds ????Angew Chem Int Ed Engl http://www.kidney.de/pget.php?&tw=1&pmid=29558562 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=29558562 #FOAvip English Wikipedia <ref>{{Cite pmid|29558562}}</ref> Catalysis with Pnictogen, Chalcogen, and Halogen Bonds #MMPMID29558562 Benz S; Poblador?Bahamonde AI; Low?Ders N; Matile S Angew Chem Int Ed Engl 2018[May]; 57 (19): 5408-12 PMID29558562show ga Halogen? and chalcogen?based ??hole interactions have recently received increased interest in non?covalent organocatalysis. However, the closely related pnictogen bonds have been neglected. In this study, we introduce conceptually simple, neutral, and monodentate pnictogen?bonding catalysts. Solution and in?silico binding studies, together with high catalytic activity in chloride abstraction reactions, yield compelling evidence for operational pnictogen bonds. The depth of the ??holes is easily varied with different substituents. Comparison with homologous halogen? and chalcogen?bonding catalysts shows an increase in activity from main group?VII to V and from row?3 to 5 in the periodic table. Pnictogen bonds from antimony thus emerged as by far the best among the elements covered, a finding that provides most intriguing perspectives for future applications in catalysis and beyond. äCatalysis with Pnictogen, Chalcogen, and Halogen Bonds (epmc).pdf DeepDyve Pubget Overpricing