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10.1002/chem.201704149

http://scihub22266oqcxt.onion/10.1002/chem.201704149
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C5923600!5923600!29053181
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suck abstract from ncbi


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pmid29053181      Chemistry 2018 ; 24 (13): 3101-12
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  • Chiral Catenanes and Rotaxanes: Fundamentals and Emerging Applications #MMPMID29053181
  • Evans NH
  • Chemistry 2018[Mar]; 24 (13): 3101-12 PMID29053181show ga
  • Molecular chirality provides a key challenge in host?guest recognition and other related chemical applications such as asymmetric catalysis. For a molecule to act as an efficient enantioselective receptor, it requires multi?point interactions between host and chiral guest, which may be achieved by an appropriate chiral 3D scaffold. As a consequence of their interlocked structure, catenanes and rotaxanes may present such a 3D scaffold, and can be chiral by inclusion of a classical chiral element and/or as a consequence of the mechanical bond. This Minireview presents illustrative examples of chiral [2]catenanes and [2]rotaxanes, and discusses where these molecules have been used in chemical applications such as chiral host?guest recognition and asymmetric catalysis.
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