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10.3762/bjoc.14.51 http://scihub22266oqcxt.onion/10.3762/bjoc.14.51 C5870144!5870144!29623126     free     free     free Deprecated: Implicit conversion from float 213.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 213.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 213.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Beilstein+J+Org+Chem 2018 ; 14 (ä): 642-7 Nephropedia Template TP {{tp|p=29623126|t=2018. Investigating radical cation chain processes in the electrocatalytic Diels?Alder reaction |pdf=|usr=}}{{29623126}} gab.com Text Investigating radical cation chain processes in the electrocatalytic Diels Alder reaction JO: Beilstein J Org Chem http://www.kidney.de/pget.php?&tw=1&pmid=29623126 #FOAvip Single electron transfer (SET)-triggered radical ion-based reactions have proven to be powerful options in synthetic organic chemistry. Although unique chain processes have been proposed in various photo- and electrochemical radical ion-based transformations, the turnover number, also referred to as catalytic efficiency, remains unclear in most cases. Herein, we disclose our investigations of radical cation chain processes in the electrocatalytic Diels?Alder reaction, leading to a scalable synthesis. A gram-scale synthesis was achieved with high current efficiency of up to 8000%. The reaction monitoring profiles showed sigmoidal curves with induction periods, suggesting the involvement of intermediate(s) in the rate determining step. Twit Text FOAVip Investigating radical cation chain processes in the electrocatalytic Diels Alder reaction ????Beilstein J Org Chem http://www.kidney.de/pget.php?&tw=1&pmid=29623126 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=29623126 #FOAvip English Wikipedia <ref>{{Cite pmid|29623126}}</ref> Investigating radical cation chain processes in the electrocatalytic Diels?Alder reaction #MMPMID29623126 Imada Y; Okada Y; Chiba K Beilstein J Org Chem 2018[]; 14 (ä): 642-7 PMID29623126show ga Single electron transfer (SET)-triggered radical ion-based reactions have proven to be powerful options in synthetic organic chemistry. Although unique chain processes have been proposed in various photo- and electrochemical radical ion-based transformations, the turnover number, also referred to as catalytic efficiency, remains unclear in most cases. Herein, we disclose our investigations of radical cation chain processes in the electrocatalytic Diels?Alder reaction, leading to a scalable synthesis. A gram-scale synthesis was achieved with high current efficiency of up to 8000%. The reaction monitoring profiles showed sigmoidal curves with induction periods, suggesting the involvement of intermediate(s) in the rate determining step. äInvestigating radical cation chain processes in the electrocatalytic D(epmc).pdf DeepDyve Pubget Overpricing