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10.1002/advs.201700152

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suck abstract from ncbi


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pmid29201609
      Adv+Sci+(Weinh) 2017 ; 4 (11 ): 1700152
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  • A New Electron Acceptor with meta-Alkoxyphenyl Side Chain for Fullerene-Free Polymer Solar Cells with 9 3% Efficiency #MMPMID29201609
  • Zhang Z ; Feng L ; Xu S ; Liu Y ; Peng H ; Zhang ZG ; Li Y ; Zou Y
  • Adv Sci (Weinh) 2017[Nov]; 4 (11 ): 1700152 PMID29201609 show ga
  • A new small molecule acceptor, m-ITIC-OR, based on indacenodithieno[3,2-b]thiophene core with meta-alkoxyphenyl side chains, is designed and synthesized. The m-ITIC-OR film shows broader and redshift absorption compared to its solution and matched energy levels with a hexafluoroquinoxaline-based polymer donor-HFQx-T. Here, polymer solar cells (PSCs) by blending an HFQx-T donor and an m-ITIC-OR acceptor as an active layer deliver the power conversion efficiency (PCE) of 6.36% without any posttreatment. The investigations demonstrate that the HFQx-T:m-ITIC-OR blend films possess higher and more balanced charge mobility, negligible bimolecular recombination, and nanoscale interpenetrating morphology after thermal annealing (TA) treatment. Through a simple TA treatment at 150 °C for 5 min, an impressive PCE of 9.3% is obtained. This efficiency is among one of the highest PCEs for additive free PSCs. This is the first time alkoxyphenyl side chain is introduced into nonfullerene electron acceptor; more interestingly, the new electron acceptor (m-ITIC-OR) in this work shows a great potential for highly efficient photovoltaic properties.
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