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2017 ; 8
(11
): 7359-7367
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Chromium complexes for luminescence, solar cells, photoredox catalysis,
upconversion, and phototriggered NO release
#MMPMID29163886
Büldt LA
; Wenger OS
Chem Sci
2017[Nov]; 8
(11
): 7359-7367
PMID29163886
show ga
Some complexes of Cr(iii) and Cr(0) have long been known to exhibit interesting
photophysical and photochemical properties, but in the past few years important
conceptual progress was made. This Perspective focuses on the recent developments
of Cr(iii) complexes as luminophores and dyes for solar cells, their application
in photoredox catalysis, their use as sensitizers in upconversion processes, and
their performance as photochemical nitric oxide sources. The example of a
luminescent Cr(0) isocyanide complex illustrates the possibility of obtaining
photoactive analogues of d(6) metal complexes that are commonly made from
precious metals such as Ru(ii) or Ir(iii). The studies highlighted herein
illustrate the favorable excited-state properties of robust first-row transition
metal complexes with broad application potential.