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10.1038/s41467-017-00642-0 http://scihub22266oqcxt.onion/10.1038/s41467-017-00642-0 C5593820!5593820!28894086     free     free     free Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 249.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 249.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Nat+Commun 2017 ; 8 (ä): ä Nephropedia Template TP {{tp|p=28894086|t=2017. Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |pdf=|usr=}}{{28894086}} gab.com Text Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=28894086 #FOAvip The perovskite manganites AMnO3 and their doped analogues A1?xBxMnO3 (A and B?=?main group and lanthanide metals) are a fascinating family of magnetic oxides exhibiting a rich variety of properties. They are thus under intense investigation along multiple fronts, one of which is how their structural and physical properties are modified at the nanoscale. Here we show that the molecular compound [Ce3Mn8O8(O2CPh)18(HO2CPh)2] (CeIII2CeIVMnIII8; hereafter Ce3Mn8) bears a striking structural resemblance to the repeating unit seen in the perovskite manganites. Further, magnetic studies have established that Ce3Mn8 exhibits both the combination of pairwise MnIII2 ferromagnetic and antiferromagnetic exchange interactions, and the resultant spin vector alignments that are found within the 3-D C-type antiferromagnetic perovskites. First-principles theoretical calculations reveal not only the expected nearest-neighbor MnIII2 exchange couplings via superexchange pathways through bridging ligands but also an unusual, direct MnIII?CeIV?MnIII metal-to-metal channel involving the CeIVf orbitals. Twit Text FOAVip Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=28894086 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=28894086 #FOAvip English Wikipedia <ref>{{Cite pmid|28894086}}</ref> Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway #MMPMID28894086 Thuijs AE; Li XG; Wang YP; Abboud KA; Zhang XG; Cheng HP; Christou G Nat Commun 2017[]; 8 (ä): ä PMID28894086show ga The perovskite manganites AMnO3 and their doped analogues A1?xBxMnO3 (A and B?=?main group and lanthanide metals) are a fascinating family of magnetic oxides exhibiting a rich variety of properties. They are thus under intense investigation along multiple fronts, one of which is how their structural and physical properties are modified at the nanoscale. Here we show that the molecular compound [Ce3Mn8O8(O2CPh)18(HO2CPh)2] (CeIII2CeIVMnIII8; hereafter Ce3Mn8) bears a striking structural resemblance to the repeating unit seen in the perovskite manganites. Further, magnetic studies have established that Ce3Mn8 exhibits both the combination of pairwise MnIII2 ferromagnetic and antiferromagnetic exchange interactions, and the resultant spin vector alignments that are found within the 3-D C-type antiferromagnetic perovskites. First-principles theoretical calculations reveal not only the expected nearest-neighbor MnIII2 exchange couplings via superexchange pathways through bridging ligands but also an unusual, direct MnIII?CeIV?MnIII metal-to-metal channel involving the CeIVf orbitals. äMolecular analogue of the perovskite repeating unit and evidence for d(epmc).pdf DeepDyve Pubget Overpricing