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10.1038/s41467-017-00642-0 http://scihub22266oqcxt.onion/10.1038/s41467-017-00642-0 C5593820!5593820 !28894086     free     free     free Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 215.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 249.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 249.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 249.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 249.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\28894086 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       Nat+Commun 2017 ; 8 (1 ): 500 Nephropedia Template TP {{tp|p=28894086 |t=2017. Molecular analogue of the perovskite repeating unit and evidence for direct Mn(III)-Ce(IV)-Mn(III) exchange coupling pathway |pdf=|usr=}}{{28894086 }} gab.com Text Molecular analogue of the perovskite repeating unit and evidence for direct Mn(III)-Ce(IV)-Mn(III) exchange coupling pathway JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=28894086 #FOAvip The perovskite manganites AMnO(3) and their doped analogues A(1-x) B (x) MnO(3) (A and B?=?main group and lanthanide metals) are a fascinating family of magnetic oxides exhibiting a rich variety of properties. They are thus under intense investigation along multiple fronts, one of which is how their structural and physical properties are modified at the nanoscale. Here we show that the molecular compound [Ce(3)Mn(8)O(8)(O(2)CPh)(18)(HO(2)CPh)(2)] (Ce(III)(2)Ce(IV)Mn(III)(8); hereafter Ce(3)Mn(8)) bears a striking structural resemblance to the repeating unit seen in the perovskite manganites. Further, magnetic studies have established that Ce(3)Mn(8) exhibits both the combination of pairwise Mn(III)(2) ferromagnetic and antiferromagnetic exchange interactions, and the resultant spin vector alignments that are found within the 3-D C-type antiferromagnetic perovskites. First-principles theoretical calculations reveal not only the expected nearest-neighbor Mn(III)(2) exchange couplings via superexchange pathways through bridging ligands but also an unusual, direct Mn(III)-Ce(IV)-Mn(III) metal-to-metal channel involving the Ce(IV) f orbitals.Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce(3)Mn(8) cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties. Twit Text FOAVip Molecular analogue of the perovskite repeating unit and evidence for direct Mn(III)-Ce(IV)-Mn(III) exchange coupling pathway ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=28894086 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=28894086 #FOAvip English Wikipedia <ref>{{Cite pmid|28894086 }}</ref> Molecular analogue of the perovskite repeating unit and evidence for direct Mn(III)-Ce(IV)-Mn(III) exchange coupling pathway #MMPMID28894086 Thuijs AE ; Li XG ; Wang YP ; Abboud KA ; Zhang XG ; Cheng HP ; Christou G Nat Commun 2017[Sep]; 8 (1 ): 500 PMID28894086 show ga The perovskite manganites AMnO(3) and their doped analogues A(1-x) B (x) MnO(3) (A and B?=?main group and lanthanide metals) are a fascinating family of magnetic oxides exhibiting a rich variety of properties. They are thus under intense investigation along multiple fronts, one of which is how their structural and physical properties are modified at the nanoscale. Here we show that the molecular compound [Ce(3)Mn(8)O(8)(O(2)CPh)(18)(HO(2)CPh)(2)] (Ce(III)(2)Ce(IV)Mn(III)(8); hereafter Ce(3)Mn(8)) bears a striking structural resemblance to the repeating unit seen in the perovskite manganites. Further, magnetic studies have established that Ce(3)Mn(8) exhibits both the combination of pairwise Mn(III)(2) ferromagnetic and antiferromagnetic exchange interactions, and the resultant spin vector alignments that are found within the 3-D C-type antiferromagnetic perovskites. First-principles theoretical calculations reveal not only the expected nearest-neighbor Mn(III)(2) exchange couplings via superexchange pathways through bridging ligands but also an unusual, direct Mn(III)-Ce(IV)-Mn(III) metal-to-metal channel involving the Ce(IV) f orbitals.Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce(3)Mn(8) cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties. äMolecular analogue of the perovskite repeating unit and evidence for d(epmc).pdf DeepDyve Pubget Overpricing