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10.1039/c5sc02542g

http://scihub22266oqcxt.onion/10.1039/c5sc02542g
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suck abstract from ncbi

pmid28757989
      Chem+Sci 2015 ; 6 (12 ): 7305-7310
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  • CH(3)NH(3)PbI(3) perovskite single crystals: surface photophysics and their interaction with the environment #MMPMID28757989
  • Grancini G ; D'Innocenzo V ; Dohner ER ; Martino N ; Srimath Kandada AR ; Mosconi E ; De Angelis F ; Karunadasa HI ; Hoke ET ; Petrozza A
  • Chem Sci 2015[Dec]; 6 (12 ): 7305-7310 PMID28757989 show ga
  • Here we identify structural inhomogeneity on a micrometer scale across the surface of a CH(3)NH(3)PbI(3) perovskite single crystal. At the crystal edge a local distortion of the crystal lattice is responsible for a widening of the optical bandgap and faster photo-carrier recombination. These effects are inherently present at the edge of the crystal, and further enhanced upon water intercalation, as a preliminary step in the hydration of the perovskite material.
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