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10.3390/ma10040344

http://scihub22266oqcxt.onion/10.3390/ma10040344
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suck abstract from ncbi


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pmid28772705
      Materials+(Basel) 2017 ; 10 (4 ): ä
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  • LiV?O?/Polytriphenylamine Composites with Enhanced Electrochemical Performances as Cathode Materials for Rechargeable Lithium Batteries #MMPMID28772705
  • Li W ; Zhu L ; Yu Z ; Xie L ; Cao X
  • Materials (Basel) 2017[Mar]; 10 (4 ): ä PMID28772705 show ga
  • LiV?O?/polytriphenylamine composites are synthesized by a chemical oxidative polymerization process and applied as cathode materials for rechargeable lithium batteries (RLB). The structure, morphology, and electrochemical performances of the composites are characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, galvanostatic discharge/charge tests, and electrochemical impedance spectroscopy. It was found that the polytriphenylamine particles were composited with LiV?O? nanorods which acted as a protective barrier against the side reaction of LiV?O?, as well as a conductive network to reduce the reaction resistance among the LiV?O? particles. Among the LiV?O?/polytriphenylamine composites, the 17 wt % LVO/PTPAn composite showed the largest d(100) spacing. The electrochemical results showed that the 17 wt % LVO/PTPAn composite maintained a discharge capacity of 271 mAh·g(-1) at a current density of 60 mA·g(-1), as well as maintaining 236 mAh·g(-1) at 240 mA·g(-1) after 50 cycles, while the bare LiV?O? sample retained only 169 and 148 mAh·g(-1), respectively. Electrochemical impedance spectra (EIS) results implied that the 17 wt % LVO/PTPAn composite demonstrated a decreased charge transfer resistance and increased Li? ion diffusion ability, therefore manifesting better rate capability and cycling performance compared to the bare LiV?O? sample.
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