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10.3762/bjoc.13.116 http://scihub22266oqcxt.onion/10.3762/bjoc.13.116 C5496574!5496574!28694863     free     free     free Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Beilstein+J+Org+Chem 2017 ; 13 (ä): 1174-83 Nephropedia Template TP {{tp|p=28694863|t=2017. Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen |pdf=|usr=}}{{28694863}} gab.com Text Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen JO: Beilstein J Org Chem http://www.kidney.de/pget.php?&tw=1&pmid=28694863 #FOAvip A detailed electron spin resonance (ESR) analysis of mechanically induced free radicals (mechanoradicals) formation of glucose-based polysaccharides, dextran (Dx) and glycogen (Gly) was performed in comparison with amylose mechanoradicals. The ESR spectra of the samples mechanically fractured at room temperature were multicomponent. The radical concentration of Dx and Gly mechanoradicals gradually decreased during vibratory milling after reaching the maximum value. Although the molecular weight of Dx or the particle diameter of Gly steeply diminished until reaching the each maximum value of radical concentration, after that the molecular weight or the particle diameter slowly decreased. These results suggested that Dx and Gly mechanoradicals might be more unstable than amylose radicals possessing an intramolecular helical structure due to the branched structure. Twit Text FOAVip Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen ????Beilstein J Org Chem http://www.kidney.de/pget.php?&tw=1&pmid=28694863 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=28694863 #FOAvip English Wikipedia <ref>{{Cite pmid|28694863}}</ref> Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen #MMPMID28694863 Doi N; Sasai Y; Yamauchi Y; Adachi T; Kuzuya M; Kondo Si Beilstein J Org Chem 2017[]; 13 (ä): 1174-83 PMID28694863show ga A detailed electron spin resonance (ESR) analysis of mechanically induced free radicals (mechanoradicals) formation of glucose-based polysaccharides, dextran (Dx) and glycogen (Gly) was performed in comparison with amylose mechanoradicals. The ESR spectra of the samples mechanically fractured at room temperature were multicomponent. The radical concentration of Dx and Gly mechanoradicals gradually decreased during vibratory milling after reaching the maximum value. Although the molecular weight of Dx or the particle diameter of Gly steeply diminished until reaching the each maximum value of radical concentration, after that the molecular weight or the particle diameter slowly decreased. These results suggested that Dx and Gly mechanoradicals might be more unstable than amylose radicals possessing an intramolecular helical structure due to the branched structure. äKinetic analysis of mechanoradical formation during the mechanolysis o(epmc).pdf DeepDyve Pubget Overpricing