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10.1021/acsphotonics.7b00206

http://scihub22266oqcxt.onion/10.1021/acsphotonics.7b00206
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C5485798!5485798!28670601
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suck abstract from ncbi


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pmid28670601      ACS+Photonics 2017 ; 4 (6): 1453-8
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  • Light-Directed Tuning of Plasmon Resonances via Plasmon-Induced Polymerization Using Hot Electrons #MMPMID28670601
  • Ding T; Mertens J; Lombardi A; Scherman OA; Baumberg JJ
  • ACS Photonics 2017[Jun]; 4 (6): 1453-8 PMID28670601show ga
  • The precise morphology of nanoscale gaps between noble-metal nanostructures controls their resonant wavelengths. Here we show photocatalytic plasmon-induced polymerization can locally enlarge the gap size and tune the plasmon resonances. We demonstrate light-directed programmable tuning of plasmons can be self-limiting. Selective control of polymer growth around individual plasmonic nanoparticles is achieved, with simultaneous real-time monitoring of the polymerization process in situ using dark-field spectroscopy. Even without initiators present, we show light-triggered chain growth of various monomers, implying plasmon initiation of free radicals via hot-electron transfer to monomers at the Au surface. This concept not only provides a programmable way to fine-tune plasmons for many applications but also provides a window on polymer chemistry at the sub-nanoscale.
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