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10.1038/s41598-017-04576-x http://scihub22266oqcxt.onion/10.1038/s41598-017-04576-x C5484676!5484676!28652593     free     free     free Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Sci+Rep 2017 ; 7 (ä): ä Nephropedia Template TP {{tp|p=28652593|t=2017. Insight into the Electrical Double Layer of an Ionic Liquid on Graphene |pdf=|usr=}}{{28652593}} gab.com Text Insight into the Electrical Double Layer of an Ionic Liquid on Graphene JO: Sci Rep http://www.kidney.de/pget.php?&tw=1&pmid=28652593 #FOAvip Graphene is a promising next-generation conducting material with the potential to replace traditional electrode materials in supercapacitors. Since energy storage in supercapacitors relies on the electrolyte-electrode interface, here we elucidate the interfacial subnanometer structure of a single component liquid composed solely of cations and anions ? an ionic liquid- on electrified graphene. We study the effect of applied potential on the interaction between graphene and a silicon tip in an ionic liquid and describe it within the framework of the Derjaguin-Landau-Verwey-Overbeck (DLVO) theory. The energy is stored in an electrical double layer composed of an extended Stern layer, which consists of multiple ion layers over ~2 nanometers, beyond which a diffuse layer forms to compensate the applied potential on graphene. The electrical double layer significantly responds to the applied potential, and it shows the transition from overscreening to crowding of counterions at the interface at the highest applied potentials. It is proposed that surface charging occurs through the adsorption of the imidazolium cation to unbiased graphene (likely due to ?-? interactions) a?nd that the surface potential is better compensated when counterion ?crowding happens. This study scrutinizes the electrified graphene-ionic liquid interface, with implications not only in the field of energy storage, but also in lubrication. Twit Text FOAVip Insight into the Electrical Double Layer of an Ionic Liquid on Graphene ????Sci Rep http://www.kidney.de/pget.php?&tw=1&pmid=28652593 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=28652593 #FOAvip English Wikipedia <ref>{{Cite pmid|28652593}}</ref> Insight into the Electrical Double Layer of an Ionic Liquid on Graphene #MMPMID28652593 Jurado LA; Espinosa-Marzal RM Sci Rep 2017[]; 7 (ä): ä PMID28652593show ga Graphene is a promising next-generation conducting material with the potential to replace traditional electrode materials in supercapacitors. Since energy storage in supercapacitors relies on the electrolyte-electrode interface, here we elucidate the interfacial subnanometer structure of a single component liquid composed solely of cations and anions ? an ionic liquid- on electrified graphene. We study the effect of applied potential on the interaction between graphene and a silicon tip in an ionic liquid and describe it within the framework of the Derjaguin-Landau-Verwey-Overbeck (DLVO) theory. The energy is stored in an electrical double layer composed of an extended Stern layer, which consists of multiple ion layers over ~2 nanometers, beyond which a diffuse layer forms to compensate the applied potential on graphene. The electrical double layer significantly responds to the applied potential, and it shows the transition from overscreening to crowding of counterions at the interface at the highest applied potentials. It is proposed that surface charging occurs through the adsorption of the imidazolium cation to unbiased graphene (likely due to ?-? interactions) a?nd that the surface potential is better compensated when counterion ?crowding happens. This study scrutinizes the electrified graphene-ionic liquid interface, with implications not only in the field of energy storage, but also in lubrication. äInsight into the Electrical Double Layer of an Ionic Liquid on Graphen(epmc).pdf DeepDyve Pubget Overpricing