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10.1038/ncomms15341 http://scihub22266oqcxt.onion/10.1038/ncomms15341 C5465318!5465318!28580963     free     free     free Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Nat+Commun 2017 ; 8 (ä): ä Nephropedia Template TP {{tp|p=28580963|t=2017. Ultrathin metal-organic framework array for efficient electrocatalytic water splitting |pdf=|usr=}}{{28580963}} gab.com Text Ultrathin metal-organic framework array for efficient electrocatalytic water splitting JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=28580963 #FOAvip Two-dimensional metal-organic frameworks represent a family of materials with attractive chemical and structural properties, which are usually prepared in the form of bulk powders. Here we show a generic approach to fabricate ultrathin nanosheet array of metal-organic frameworks on different substrates through a dissolution?crystallization mechanism. These materials exhibit intriguing properties for electrocatalysis including highly exposed active molecular metal sites owning to ultra-small thickness of nanosheets, improved electrical conductivity and a combination of hierarchical porosity. We fabricate a nickel-iron-based metal-organic framework array, which demonstrates superior electrocatalytic performance towards oxygen evolution reaction with a small overpotential of 240?mV at 10?mA?cm?2, and robust operation for 20,000?s with no detectable activity decay. Remarkably, the turnover frequency of the electrode is 3.8?s?1 at an overpotential of 400?mV. We further demonstrate the promise of these electrodes for other important catalytic reactions including hydrogen evolution reaction and overall water splitting. Twit Text FOAVip Ultrathin metal-organic framework array for efficient electrocatalytic water splitting ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=28580963 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=28580963 #FOAvip English Wikipedia <ref>{{Cite pmid|28580963}}</ref> Ultrathin metal-organic framework array for efficient electrocatalytic water splitting #MMPMID28580963 Duan J; Chen S; Zhao C Nat Commun 2017[]; 8 (ä): ä PMID28580963show ga Two-dimensional metal-organic frameworks represent a family of materials with attractive chemical and structural properties, which are usually prepared in the form of bulk powders. Here we show a generic approach to fabricate ultrathin nanosheet array of metal-organic frameworks on different substrates through a dissolution?crystallization mechanism. These materials exhibit intriguing properties for electrocatalysis including highly exposed active molecular metal sites owning to ultra-small thickness of nanosheets, improved electrical conductivity and a combination of hierarchical porosity. We fabricate a nickel-iron-based metal-organic framework array, which demonstrates superior electrocatalytic performance towards oxygen evolution reaction with a small overpotential of 240?mV at 10?mA?cm?2, and robust operation for 20,000?s with no detectable activity decay. Remarkably, the turnover frequency of the electrode is 3.8?s?1 at an overpotential of 400?mV. We further demonstrate the promise of these electrodes for other important catalytic reactions including hydrogen evolution reaction and overall water splitting. äUltrathin metal-organic framework array for efficient electrocatalytic(epmc).pdf DeepDyve Pubget Overpricing