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10.1038/ncomms15636

http://scihub22266oqcxt.onion/10.1038/ncomms15636
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suck abstract from ncbi


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pmid28548100
      Nat+Commun 2017 ; 8 (ä): 15636
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  • Hierarchically structured lithium titanate for ultrafast charging in long-life high capacity batteries #MMPMID28548100
  • Odziomek M ; Chaput F ; Rutkowska A ; ?wierczek K ; Olszewska D ; Sitarz M ; Lerouge F ; Parola S
  • Nat Commun 2017[May]; 8 (ä): 15636 PMID28548100 show ga
  • High-performance Li-ion batteries require materials with well-designed and controlled structures on nanometre and micrometre scales. Electrochemical properties can be enhanced by reducing crystallite size and by manipulating structure and morphology. Here we show a method for preparing hierarchically structured Li(4)Ti(5)O(12) yielding nano- and microstructure well-suited for use in lithium-ion batteries. Scalable glycothermal synthesis yields well-crystallized primary 4-8?nm nanoparticles, assembled into porous secondary particles. X-ray photoelectron spectroscopy reveals presence of Ti(+4) only; combined with chemical analysis showing lithium deficiency, this suggests oxygen non-stoichiometry. Electron microscopy confirms hierarchical morphology of the obtained material. Extended cycling tests in half cells demonstrates capacity of 170?mAh?g(-1) and no sign of capacity fading after 1,000 cycles at 50C rate (charging completed in 72?s). The particular combination of nanostructure, microstructure and non-stoichiometry for the prepared lithium titanate is believed to underlie the observed electrochemical performance of material.
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