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10.1038/ncomms15174

http://scihub22266oqcxt.onion/10.1038/ncomms15174
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C5418575!5418575!28462925
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suck abstract from ncbi

pmid28462925      Nat+Commun 2017 ; 8 (ä): ä
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  • Directly converting CO2 into a gasoline fuel #MMPMID28462925
  • Wei J; Ge Q; Yao R; Wen Z; Fang C; Guo L; Xu H; Sun J
  • Nat Commun 2017[]; 8 (ä): ä PMID28462925show ga
  • The direct production of liquid fuels from CO2 hydrogenation has attracted enormous interest for its significant roles in mitigating CO2 emissions and reducing dependence on petrochemicals. Here we report a highly efficient, stable and multifunctional Na?Fe3O4/HZSM-5 catalyst, which can directly convert CO2 to gasoline-range (C5?C11) hydrocarbons with selectivity up to 78% of all hydrocarbons while only 4% methane at a CO2 conversion of 22% under industrial relevant conditions. It is achieved by a multifunctional catalyst providing three types of active sites (Fe3O4, Fe5C2 and acid sites), which cooperatively catalyse a tandem reaction. More significantly, the appropriate proximity of three types of active sites plays a crucial role in the successive and synergetic catalytic conversion of CO2 to gasoline. The multifunctional catalyst, exhibiting a remarkable stability for 1,000 h on stream, definitely has the potential to be a promising industrial catalyst for CO2 utilization to liquid fuels.
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