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.jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117 Adv+Sci+(Weinh)
2017 ; 4
(4
): 1600371
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Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic
and Photocatalytic Water Splitting
#MMPMID28435777
Wang W
; Xu X
; Zhou W
; Shao Z
Adv Sci (Weinh)
2017[Apr]; 4
(4
): 1600371
PMID28435777
show ga
The development of clean and renewable energy materials as alternatives to fossil
fuels is foreseen as a potential solution to the crucial problems of
environmental pollution and energy shortages. Hydrogen is an ideal energy
material for the future, and water splitting using solar/electrical energy is one
way to generate hydrogen. Metal-organic frameworks (MOFs) are a class of porous
materials with unique properties that have received rapidly growing attention in
recent years for applications in water splitting due to their remarkable design
flexibility, ultra-large surface-to-volume ratios and tunable pore channels. This
review focuses on recent progress in the application of MOFs in electrocatalytic
and photocatalytic water splitting for hydrogen generation, including both oxygen
and hydrogen evolution. It starts with the fundamentals of electrocatalytic and
photocatalytic water splitting and the related factors to determine the catalytic
activity. The recent progress in the exploitation of MOFs for water splitting is
then summarized, and strategies for designing MOF-based catalysts for
electrocatalytic and photocatalytic water splitting are presented. Finally, major
challenges in the field of water splitting are highlighted, and some perspectives
of MOF-based catalysts for water splitting are proposed.