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10.1038/srep09130

http://scihub22266oqcxt.onion/10.1038/srep09130
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C5390902!5390902!25773684
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suck abstract from ncbi


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pmid25773684      Sci+Rep 2015 ; 5 (ä): ä
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  • Light Illuminated ??Fe2O3/Pt Nanoparticles as Water Activation Agent for Photoelectrochemical Water Splitting #MMPMID25773684
  • Li X; Wang Z; Zhang Z; Chen L; Cheng J; Ni W; Wang B; Xie E
  • Sci Rep 2015[]; 5 (ä): ä PMID25773684show ga
  • The photoelectrochemical (PEC) water splitting is hampered by strong bonds of H2O molecules and low ionic conductivity of pure water. The photocatalysts dispersed in pure water can serve as a water activation agent, which provides an alternative pathway to overcome such limitations. Here we report that the light illuminated ??Fe2O3/Pt nanoparticles may produce a reservoir of reactive intermediates including H2O2, ·OH, OH? and H+ capable of promoting the pure water reduction/oxidation half?reactions at cathode and highly photocatalytic?active TiO2/In2S3/AgInS2 photoanode, respectively. Remarkable photocurrent enhancement has been obtained with ??Fe2O3/Pt as water activation agent. The use of ??Fe2O3/Pt to promote the reactivity of pure water represents a new paradigm for reproducible hydrogen fuel provision by PEC water splitting, allowing efficient splitting of pure water without adding of corrosive chemicals or sacrificial agent.
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