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10.1038/srep46141

http://scihub22266oqcxt.onion/10.1038/srep46141
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C5388881!5388881!28401890
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suck abstract from ncbi


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pmid28401890      Sci+Rep 2017 ; 7 (ä): ä
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  • Ultra-high open-circuit voltage of perovskite solar cells induced by nucleation thermodynamics on rough substrates #MMPMID28401890
  • Li Y; Ding B; Chu QQ; Yang GJ; Wang M; Li CX; Li CJ
  • Sci Rep 2017[]; 7 (ä): ä PMID28401890show ga
  • To obtain high performance CH3NH3PbI3 perovskite solar cells, it is highly important to realise a high open-circuit voltage. Calculation results based on a modified diode model have indicated that a low bare ratio ? of the perovskite film is the most important factor determining the open-circuit voltage, where ? is defined as the ratio of the projection of the uncovered area of the perovskite film to the apparent area of the total substrate surface. To realise a low ?, we investigate the nucleation behaviour of crystals on rough substrates. The analysis results predict that, when CH3NH3PbI3 is deposited on conventional transparent conductive oxide substrates such as fluorine-doped tin oxide, preferential heterogeneous nucleation will occur on the concave regions of the substrate; then, depending on the subsequent growth step, full coverage of the perovskite film at both the macroscopic and microscopic scales is realised. As a result, an ultra-high open-circuit voltage, i.e., 1.20?V, can be achieved in devices using the full coverage CH3NH3PbI3 film. The thermodynamics theory of precipitation nucleation should shed light on solution engineering of thin films.
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