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2017 ; 7
(ä): 44629
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Optical determination of Shockley-Read-Hall and interface recombination currents
in hybrid perovskites
#MMPMID28317883
Sarritzu V
; Sestu N
; Marongiu D
; Chang X
; Masi S
; Rizzo A
; Colella S
; Quochi F
; Saba M
; Mura A
; Bongiovanni G
Sci Rep
2017[Mar]; 7
(ä): 44629
PMID28317883
show ga
Metal-halide perovskite solar cells rival the best inorganic solar cells in power
conversion efficiency, providing the outlook for efficient, cheap devices. In
order for the technology to mature and approach the ideal Shockley-Queissier
efficiency, experimental tools are needed to diagnose what processes limit
performances, beyond simply measuring electrical characteristics often affected
by parasitic effects and difficult to interpret. Here we study the microscopic
origin of recombination currents causing photoconversion losses with an
all-optical technique, measuring the electron-hole free energy as a function of
the exciting light intensity. Our method allows assessing the ideality factor and
breaks down the electron-hole recombination current into bulk defect and
interface contributions, providing an estimate of the limit photoconversion
efficiency, without any real charge current flowing through the device. We
identify Shockley-Read-Hall recombination as the main decay process in insulated
perovskite layers and quantify the additional performance degradation due to
interface recombination in heterojunctions.