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10.1038/ncomms14555

http://scihub22266oqcxt.onion/10.1038/ncomms14555
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C5333356!5333356!28240286
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suck abstract from ncbi


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pmid28240286      Nat+Commun 2017 ; 8 (ä): ä
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  • Synergy of ammonium chloride and moisture on perovskite crystallization for efficient printable mesoscopic solar cells #MMPMID28240286
  • Rong Y; Hou X; Hu Y; Mei A; Liu L; Wang P; Han H
  • Nat Commun 2017[]; 8 (ä): ä PMID28240286show ga
  • Organometal lead halide perovskites have been widely used as the light harvester for high-performance solar cells. However, typical perovskites of methylammonium lead halides (CH3NH3PbX3, X=Cl, Br, I) are usually sensitive to moisture in ambient air, and thus require an inert atmosphere to process. Here we demonstrate a moisture-induced transformation of perovskite crystals in a triple-layer scaffold of TiO2/ZrO2/Carbon to fabricate printable mesoscopic solar cells. An additive of ammonium chloride (NH4Cl) is employed to assist the crystallization of perovskite, wherein the formation and transition of intermediate CH3NH3X·NH4PbX3(H2O)2 (X=I or Cl) enables high-quality perovskite CH3NH3PbI3 crystals with preferential growth orientation. Correspondingly, the intrinsic perovskite devices based on CH3NH3PbI3 achieve an efficiency of 15.6% and a lifetime of over 130 days in ambient condition with 30% relative humidity. This ambient-processed printable perovskite solar cell provides a promising prospect for mass production, and will promote the development of perovskite-based photovoltaics.
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