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10.1038/ncomms14525

http://scihub22266oqcxt.onion/10.1038/ncomms14525
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C5321725!5321725!28216636
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suck abstract from ncbi


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pmid28216636      Nat+Commun 2017 ; 8 (ä): ä
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  • Room temperature organic magnets derived from sp3 functionalized graphene #MMPMID28216636
  • Tu?ek J; Holá K; Bourlinos AB; B?o?ski P; Bakandritsos A; Ugolotti J; Dubecký M; Karlický F; Ranc V; ?épe K; Otyepka M; Zbo?il R
  • Nat Commun 2017[]; 8 (ä): ä PMID28216636show ga
  • Materials based on metallic elements that have d orbitals and exhibit room temperature magnetism have been known for centuries and applied in a huge range of technologies. Development of room temperature carbon magnets containing exclusively sp orbitals is viewed as great challenge in chemistry, physics, spintronics and materials science. Here we describe a series of room temperature organic magnets prepared by a simple and controllable route based on the substitution of fluorine atoms in fluorographene with hydroxyl groups. Depending on the chemical composition (an F/OH ratio) and sp3 coverage, these new graphene derivatives show room temperature antiferromagnetic ordering, which has never been observed for any sp-based materials. Such 2D magnets undergo a transition to a ferromagnetic state at low temperatures, showing an extraordinarily high magnetic moment. The developed theoretical model addresses the origin of the room temperature magnetism in terms of sp2-conjugated diradical motifs embedded in an sp3 matrix and superexchange interactions via ?OH functionalization.
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