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10.1007/s41061-016-0030-6 http://scihub22266oqcxt.onion/10.1007/s41061-016-0030-6 C5107260!5107260 !27573270     free     free     free Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\27573270 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       Top+Curr+Chem+(Cham) 2016 ; 374 (3 ): 30 Nephropedia Template TP {{tp|p=27573270 |t=2016. Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities |pdf=|usr=}}{{27573270 }} gab.com Text Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities JO: Top Curr Chem (Cham) http://www.kidney.de/pget.php?&tw=1&pmid=27573270 #FOAvip Proton-coupled electron transfers (PCETs) are unconventional redox processes in which both protons and electrons are exchanged, often in a concerted elementary step. While PCET is now recognized to play a central a role in biological redox catalysis and inorganic energy conversion technologies, its applications in organic synthesis are only beginning to be explored. In this chapter, we aim to highlight the origins, development, and evolution of the PCET processes most relevant to applications in organic synthesis. Particular emphasis is given to the ability of PCET to serve as a non-classical mechanism for homolytic bond activation that is complimentary to more traditional hydrogen atom transfer processes, enabling the direct generation of valuable organic radical intermediates directly from their native functional group precursors under comparatively mild catalytic conditions. The synthetically advantageous features of PCET reactivity are described in detail, along with examples from the literature describing the PCET activation of common organic functional groups. Twit Text FOAVip Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities ????Top Curr Chem (Cham) http://www.kidney.de/pget.php?&tw=1&pmid=27573270 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=27573270 #FOAvip English Wikipedia <ref>{{Cite pmid|27573270 }}</ref> Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities #MMPMID27573270 Miller DC ; Tarantino KT ; Knowles RR Top Curr Chem (Cham) 2016[Jun]; 374 (3 ): 30 PMID27573270 show ga Proton-coupled electron transfers (PCETs) are unconventional redox processes in which both protons and electrons are exchanged, often in a concerted elementary step. While PCET is now recognized to play a central a role in biological redox catalysis and inorganic energy conversion technologies, its applications in organic synthesis are only beginning to be explored. In this chapter, we aim to highlight the origins, development, and evolution of the PCET processes most relevant to applications in organic synthesis. Particular emphasis is given to the ability of PCET to serve as a non-classical mechanism for homolytic bond activation that is complimentary to more traditional hydrogen atom transfer processes, enabling the direct generation of valuable organic radical intermediates directly from their native functional group precursors under comparatively mild catalytic conditions. The synthetically advantageous features of PCET reactivity are described in detail, along with examples from the literature describing the PCET activation of common organic functional groups. |Coordination Complexes/chemistry [MESH] |Electron Transport [MESH] |Electrons [MESH] |Hydrogen/chemistry [MESH] |Indoles/chemical synthesis/chemistry [MESH] |Organic Chemicals/chemical synthesis/*chemistry [MESH] |Oxidation-Reduction [MESH] |Phenols/chemical synthesis/chemistry [MESH] |Protons [MESH]Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, (epmc).pdf DeepDyve Pubget Overpricing