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Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 European+J+Org+Chem 2016 ; 2016 (25): 4328-37 Nephropedia Template TP
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The Amadori Rearrangement for Carbohydrate Conjugation: Scope and Limitations #MMPMID27840588
European J Org Chem 2016[Sep]; 2016 (25): 4328-37 PMID27840588show ga
The Amadori rearrangement was investigated for the synthesis of C?glycosyl?type neoglycoconjugates. Various amines including diamines, amino?functionalized glycosides, lysine derivatives, and peptides were conjugated with two different heptoses to generate non?natural C?glycosyl?type glycoconjugates of the d?gluco and d?manno series. With these studies, the scope and limitations of the Amadori rearrangement as a conjugation method have been exemplified with respect to the carbohydrate substrate, as well as the amino components.