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10.1088/1468-6996/10/2/024304

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suck abstract from ncbi


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pmid27877277
      Sci+Technol+Adv+Mater 2009 ; 10 (2 ): 024304
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  • Variety of valence bond states formed of frustrated spins on triangular lattices based on a two-level system Pd(dmit)(2) #MMPMID27877277
  • Tamura M ; Kato R
  • Sci Technol Adv Mater 2009[Apr]; 10 (2 ): 024304 PMID27877277 show ga
  • Recent studies on the physical properties of the triangular system based on the Pd(dmit)(2) salts (dmit=1,3-dithiole-2-thione-4,5-dithiolate) are reviewed. Quantum chemical architectures of the Pd(dmit)(2) molecule and its dimer are introduced with emphasis on the strong dimerization of a two-level system, which provides unique physical properties of the salts. The magnetic properties are outlined in view of the magneto-structural correlation specific to the frustrated spin systems. Some newly discovered ground states and their origins are discussed, for which the valence bond formation plays a key role. Among them, the two-level structure is crucial for the novel charge-separated state found in two salts. The valence bond ordering, similar to the spin-Peierls transition, has been found in a two-dimensional frustrated spin system. The physical aspects and possible relation to the pressure-induced superconductivity are discussed.
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