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2016 ; 3
(6
): 1600024
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Plasmon-Mediated Solar Energy Conversion via Photocatalysis in Noble
Metal/Semiconductor Composites
#MMPMID27818901
Wang M
; Ye M
; Iocozzia J
; Lin C
; Lin Z
Adv Sci (Weinh)
2016[Jun]; 3
(6
): 1600024
PMID27818901
show ga
Plasmonics has remained a prominent and growing field over the past several
decades. The coupling of various chemical and photo phenomenon has sparked
considerable interest in plasmon-mediated photocatalysis. Given plasmonic
photocatalysis has only been developed for a relatively short period,
considerable progress has been made in improving the absorption across the full
solar spectrum and the efficiency of photo-generated charge carrier separation.
With recent advances in fundamental (i.e., mechanisms) and experimental studies
(i.e., the influence of size, geometry, surrounding dielectric field, etc.) on
plasmon-mediated photocatalysis, the rational design and synthesis of
metal/semiconductor hybrid nanostructure photocatalysts has been realized. This
review seeks to highlight the recent impressive developments in plasmon-mediated
photocatalytic mechanisms (i.e., Schottky junction, direct electron transfer,
enhanced local electric field, plasmon resonant energy transfer, and scattering
and heating effects), summarize a set of factors (i.e., size, geometry,
dielectric environment, loading amount and composition of plasmonic metal, and
nanostructure and properties of semiconductors) that largely affect plasmonic
photocatalysis, and finally conclude with a perspective on future directions
within this rich field of research.