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10.1016/j.fluid.2016.04.009 http://scihub22266oqcxt.onion/10.1016/j.fluid.2016.04.009 C5036539/?report=reader!5036539!27682333     free     free     free Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=27682333&cmd=llinks): Failed to open stream: HTTP request failed! 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The Effect of n vs iso Isomerization on the Thermophysical Properties of Aromatic and Non-aromatic Ionic Liquids |pdf=|usr=}}{{27682333}} gab.com Text The Effect of n vs iso Isomerization on the Thermophysical Properties of Aromatic and Non-aromatic Ionic Liquids JO: Fluid Phase Equilib http://www.kidney.de/pget.php?&tw=1&pmid=27682333 #FOAvip This work explores the n vs. iso isomerization effects on the physicochemical properties of different families of ionic liquids (ILs) with variable aromaticity and ring size. This study comprises the experimental measurements, in a wide temperature range, of the ILs? thermal behavior, heat capacities, densities, refractive indices, surface tensions, and viscosities. The results here reported show that the presence of the iso-alkyl group leads to an increase of the temperature of the glass transition, Tg. The iso-pyrrolidinium (5 atoms ring cation core) and iso-piperidinium (6 atoms ring cation core) ILs present a strong differentiation in the enthalpy and entropy of melting. Non-aromatic ILs have higher molar heat capacities due to the increase of the atomic contribution, whereas it was not found any significant differentiation between the n and iso-alkyl isomers. A small increase of the surface tension was observed for the non-aromatic ILs, which could be related to their higher cohesive energy of the bulk, while the lower surface entropy observed for the iso isomers indicates a structural resemblance between the IL bulk and surface. The significant differentiation between ILs with a 5 and 6 atoms ring cation in the n-alkyl series (where 5 atoms ring cations have higher surface entropy) is an indication of a more efficient arrangement of the non-polar region at the surface in ILs with smaller cation cores. The ILs constituted by non-aromatic piperidinium cation, and iso-alkyl isomers were found to be the most viscous among the studied ILs due to their higher energy barriers for shear stress. Twit Text FOAVip The Effect of n vs iso Isomerization on the Thermophysical Properties of Aromatic and Non-aromatic Ionic Liquids ????Fluid Phase Equilib http://www.kidney.de/pget.php?&tw=1&pmid=27682333 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=27682333 #FOAvip English Wikipedia <ref>{{Cite pmid|27682333}}</ref> The Effect of n vs iso Isomerization on the Thermophysical Properties of Aromatic and Non-aromatic Ionic Liquids #MMPMID27682333 Rodrigues AS; Almeida HFD; Freire MG; Lopes-da-Silva JA; Coutinho JAP; Santos LMNBF Fluid Phase Equilib 2016[Sep]; 423 (ä): 190-202 PMID27682333show ga This work explores the n vs. iso isomerization effects on the physicochemical properties of different families of ionic liquids (ILs) with variable aromaticity and ring size. This study comprises the experimental measurements, in a wide temperature range, of the ILs? thermal behavior, heat capacities, densities, refractive indices, surface tensions, and viscosities. The results here reported show that the presence of the iso-alkyl group leads to an increase of the temperature of the glass transition, Tg. The iso-pyrrolidinium (5 atoms ring cation core) and iso-piperidinium (6 atoms ring cation core) ILs present a strong differentiation in the enthalpy and entropy of melting. Non-aromatic ILs have higher molar heat capacities due to the increase of the atomic contribution, whereas it was not found any significant differentiation between the n and iso-alkyl isomers. A small increase of the surface tension was observed for the non-aromatic ILs, which could be related to their higher cohesive energy of the bulk, while the lower surface entropy observed for the iso isomers indicates a structural resemblance between the IL bulk and surface. The significant differentiation between ILs with a 5 and 6 atoms ring cation in the n-alkyl series (where 5 atoms ring cations have higher surface entropy) is an indication of a more efficient arrangement of the non-polar region at the surface in ILs with smaller cation cores. The ILs constituted by non-aromatic piperidinium cation, and iso-alkyl isomers were found to be the most viscous among the studied ILs due to their higher energy barriers for shear stress. äThe Effect of n vs iso Isomerization on the Thermophysical Properties(epmc).pdf DeepDyve Pubget Overpricing