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10.1371/journal.pone.0162849 http://scihub22266oqcxt.onion/10.1371/journal.pone.0162849 C5017724!5017724!27611817     free     free     free Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       PLoS+One 2016 ; 11 (9): ä Nephropedia Template TP {{tp|p=27611817|t=2016. Effect of Carboxymethylation on the Rheological Properties of Hyaluronan |pdf=|usr=}}{{27611817}} gab.com Text Effect of Carboxymethylation on the Rheological Properties of Hyaluronan JO: PLoS One http://www.kidney.de/pget.php?&tw=1&pmid=27611817 #FOAvip Chemical modifications made to hyaluronan to enable covalent crosslinking to form a hydrogel or to attach other molecules may alter the physical properties as well, which have physiological importance. Here we created carboxymethyl hyaluronan (CMHA) with varied degree of modification and investigated the effect on the viscosity of CMHA solutions. Viscosity decreased initially as modification increased, with a minimum viscosity for about 30?40% modification. This was followed by an increase in viscosity around 45?50% modification. The pH of the solution had a variable effect on viscosity, depending on the degree of carboxymethyl modification and buffer. The presence of phosphates in the buffer led to decreased viscosity. We also compared large-scale production lots of CMHA to lab-scale and found that large-scale required extended reaction times to achieve the same degree of modification. Finally, thiolated CMHA was disulfide crosslinked to create hydrogels with increased viscosity and shear-thinning aspects compared to CMHA solutions. Twit Text FOAVip Effect of Carboxymethylation on the Rheological Properties of Hyaluronan ????PLoS One http://www.kidney.de/pget.php?&tw=1&pmid=27611817 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=27611817 #FOAvip English Wikipedia <ref>{{Cite pmid|27611817}}</ref> Effect of Carboxymethylation on the Rheological Properties of Hyaluronan #MMPMID27611817 Wendling RJ; Christensen AM; Quast AD; Atzet SK; Mann BK PLoS One 2016[]; 11 (9): ä PMID27611817show ga Chemical modifications made to hyaluronan to enable covalent crosslinking to form a hydrogel or to attach other molecules may alter the physical properties as well, which have physiological importance. Here we created carboxymethyl hyaluronan (CMHA) with varied degree of modification and investigated the effect on the viscosity of CMHA solutions. Viscosity decreased initially as modification increased, with a minimum viscosity for about 30?40% modification. This was followed by an increase in viscosity around 45?50% modification. The pH of the solution had a variable effect on viscosity, depending on the degree of carboxymethyl modification and buffer. The presence of phosphates in the buffer led to decreased viscosity. We also compared large-scale production lots of CMHA to lab-scale and found that large-scale required extended reaction times to achieve the same degree of modification. Finally, thiolated CMHA was disulfide crosslinked to create hydrogels with increased viscosity and shear-thinning aspects compared to CMHA solutions. äEffect of Carboxymethylation on the Rheological Properties of Hyaluron(epmc).pdf DeepDyve Pubget Overpricing