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10.1038/ncomms12552

http://scihub22266oqcxt.onion/10.1038/ncomms12552
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C4996976!4996976!27550091
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suck abstract from ncbi


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pmid27550091      Nat+Commun 2016 ; 7 (ä): ä
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  • Hybrid bio-photo-electro-chemical cells for solar water splitting #MMPMID27550091
  • Pinhassi RI; Kallmann D; Saper G; Dotan H; Linkov A; Kay A; Liveanu V; Schuster G; Adir N; Rothschild A
  • Nat Commun 2016[]; 7 (ä): ä PMID27550091show ga
  • Photoelectrochemical water splitting uses solar power to decompose water to hydrogen and oxygen. Here we show how the photocatalytic activity of thylakoid membranes leads to overall water splitting in a bio-photo-electro-chemical (BPEC) cell via a simple process. Thylakoids extracted from spinach are introduced into a BPEC cell containing buffer solution with ferricyanide. Upon solar-simulated illumination, water oxidation takes place and electrons are shuttled by the ferri/ferrocyanide redox couple from the thylakoids to a transparent electrode serving as the anode, yielding a photocurrent density of 0.5?mA?cm?2. Hydrogen evolution occurs at the cathode at a bias as low as 0.8?V. A tandem cell comprising the BPEC cell and a Si photovoltaic module achieves overall water splitting with solar to hydrogen efficiency of 0.3%. These results demonstrate the promise of combining natural photosynthetic membranes and man-made photovoltaic cells in order to convert solar power into hydrogen fuel.
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