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Deprecated: Implicit conversion from float 278.79999999999995 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Org+Lett 2016 ; 18 (11): 2572-5 Nephropedia Template TP
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Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis #MMPMID27218884
Karimi-Nami R; Tellis JC; Molander GA
Org Lett 2016[Jun]; 18 (11): 2572-5 PMID27218884show ga
Protecting-group-independent cross-coupling of ?-alkoxyalkyl- and ?-acyloxyalkyltrifluoroborates with aryl and heteroaryl bromides is achieved through application of photoredox/nickel dual catalysis. Reactions occur under exceptionally mild conditions, with outstanding functional group compatibility and excellent observed tolerance of heteroarenes. This method offers expedient access to protected secondary benzylic alcohol motifs bearing benzyl, pivaloyl, and N,N-diisopropylcarbamoyl protecting groups.