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2016 ; 6
(ä): 26660
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Large-Scale Production of Large-Size Atomically Thin Semiconducting Molybdenum
Dichalcogenide Sheets in Water and Its Application for Supercapacitor
#MMPMID27225297
Chen YX
; Wu CW
; Kuo TY
; Chang YL
; Jen MH
; Chen IW
Sci Rep
2016[May]; 6
(ä): 26660
PMID27225297
show ga
To progress from laboratory research to commercial applications, it is necessary
to develop an effective method to prepare large quantities and high-quality of
the large-size atomically thin molybdenum dichalcogenides (MoS2). Aqueous-phase
processes provide a viable method for producing thin MoS2 sheets using
organolithium-assisted exfoliation; unfortunately, this method is hindered by
changing pristine semiconducting 2H phase to distorted metallic 1T phase.
Recovery of the intrinsic 2H phase typically involves heating of the 1T MoS2
sheets on solid substrates at high temperature. This has restricted and hindered
the utilization of 2H phase MoS2 sheets suspensions. Here, we demonstrate that
the synergistic effect of the rigid planar structure and charged nature of
organic salt such as imidazole (ImH) can be successfully used to produce
atomically thin 2H-MoS2 sheets suspension in water. Moreover, lateral size and
area of the exfoliated sheet can be up to 50??m and 1000??m(2), respectively.
According to the XPS measurements, nearly 100% of the 2H-MoS2 sheets was
successfully prepared. A composite paper supercapacitor using the exfoliated
2H-MoS2 and carbon nanotubes delivered a superior volumetric capacitance of
~410?F/cm(3). Therefore, the organic salts-assisted liquid-phase exfoliation has
great potential for large-scale production of 2H-MoS2 suspensions for
supercapacitor application.