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10.1038/ncomms11559 http://scihub22266oqcxt.onion/10.1038/ncomms11559 C4869171!4869171!27174162     free     free     free Deprecated: Implicit conversion from float 227.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 227.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 227.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 227.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Nat+Commun 2016 ; 7 (ä): ä Nephropedia Template TP {{tp|p=27174162|t=2016. Van der Waals interactions and the limits of isolated atom models at interfaces |pdf=|usr=}}{{27174162}} gab.com Text Van der Waals interactions and the limits of isolated atom models at interfaces JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=27174162 #FOAvip Van der Waals forces are among the weakest, yet most decisive interactions governing condensation and aggregation processes and the phase behaviour of atomic and molecular matter. Understanding the resulting structural motifs and patterns has become increasingly important in studies of the nanoscale regime. Here we measure the paradigmatic van der Waals interactions represented by the noble gas atom pairs Ar?Xe, Kr?Xe and Xe?Xe with a Xe-functionalized tip of an atomic force microscope at low temperature. Individual rare gas atoms were fixed at node sites of a surface-confined two-dimensional metal?organic framework. We found that the magnitude of the measured force increased with the atomic radius, yet detailed simulation by density functional theory revealed that the adsorption induced charge redistribution strengthened the van der Waals forces by a factor of up to two, thus demonstrating the limits of a purely atomic description of the interaction in these representative systems. Twit Text FOAVip Van der Waals interactions and the limits of isolated atom models at interfaces ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=27174162 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=27174162 #FOAvip English Wikipedia <ref>{{Cite pmid|27174162}}</ref> Van der Waals interactions and the limits of isolated atom models at interfaces #MMPMID27174162 Kawai S; Foster AS; Björkman T; Nowakowska S; Björk J; Canova FF; Gade LH; Jung TA; Meyer E Nat Commun 2016[]; 7 (ä): ä PMID27174162show ga Van der Waals forces are among the weakest, yet most decisive interactions governing condensation and aggregation processes and the phase behaviour of atomic and molecular matter. Understanding the resulting structural motifs and patterns has become increasingly important in studies of the nanoscale regime. Here we measure the paradigmatic van der Waals interactions represented by the noble gas atom pairs Ar?Xe, Kr?Xe and Xe?Xe with a Xe-functionalized tip of an atomic force microscope at low temperature. Individual rare gas atoms were fixed at node sites of a surface-confined two-dimensional metal?organic framework. We found that the magnitude of the measured force increased with the atomic radius, yet detailed simulation by density functional theory revealed that the adsorption induced charge redistribution strengthened the van der Waals forces by a factor of up to two, thus demonstrating the limits of a purely atomic description of the interaction in these representative systems. äVan der Waals interactions and the limits of isolated atom models at i(epmc).pdf DeepDyve Pubget Overpricing