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2016 ; 6
(ä): 26262
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Interface Engineering of Organic Schottky Barrier Solar Cells and Its Application
in Enhancing Performances of Planar Heterojunction Solar Cells
#MMPMID27185635
Jin F
; Su Z
; Chu B
; Cheng P
; Wang J
; Zhao H
; Gao Y
; Yan X
; Li W
Sci Rep
2016[May]; 6
(ä): 26262
PMID27185635
show ga
In this work, we describe the performance of organic Schottky barrier solar cells
with the structure of ITO/molybdenum oxide (MoOx)/boron subphthalocyanine
chloride (SubPc)/bathophenanthroline (BPhen)/Al. The SubPc-based Schottky barrier
solar cells exhibited a short-circuit current density (Jsc) of 2.59?mA/cm(2), an
open-circuit voltage (Voc) of 1.06?V, and a power conversion efficiency (PCE) of
0.82% under simulated AM1.5?G solar illumination at 100?mW/cm(2). Device
performance was substantially enhanced by simply inserting thin organic hole
transport material into the interface of MoOx and SubPc. The optimized devices
realized a 180% increase in PCE of 2.30% and a peak Voc as high as 1.45?V was
observed. We found that the improvement is due to the exciton and electron
blocking effect of the interlayer and its thickness plays a vital role in
balancing charge separation and suppressing quenching effect. Moreover, applying
such interface engineering into MoOx/SubPc/C60 based planar heterojunction cells
substantially enhanced the PCE of the device by 44%, from 3.48% to 5.03%.
Finally, we also investigated the requirements of the interface material for
Schottky barrier modification.