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10.1038/ncomms11299 http://scihub22266oqcxt.onion/10.1038/ncomms11299 C4838886!4838886!27090355     free     free     free Deprecated: Implicit conversion from float 231.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 231.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 231.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Nat+Commun 2016 ; 7 (ä): ä Nephropedia Template TP {{tp|p=27090355|t=2016. Supramolecular macrocycles reversibly assembled by Te?O chalcogen bonding |pdf=|usr=}}{{27090355}} gab.com Text Supramolecular macrocycles reversibly assembled by Te O chalcogen bonding JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=27090355 #FOAvip Organic molecules with heavy main-group elements frequently form supramolecular links to electron-rich centres. One particular case of such interactions is halogen bonding. Most studies of this phenomenon have been concerned with either dimers or infinitely extended structures (polymers and lattices) but well-defined cyclic structures remain elusive. Here we present oligomeric aggregates of heterocycles that are linked by chalcogen-centered interactions and behave as genuine macrocyclic species. The molecules of 3-methyl-5-phenyl-1,2-tellurazole 2-oxide assemble a variety of supramolecular aggregates that includes cyclic tetramers and hexamers, as well as a helical polymer. In all these aggregates, the building blocks are connected by Te?O?N bridges. Nuclear magnetic resonance spectroscopic experiments demonstrate that the two types of annular aggregates are persistent in solution. These self-assembled structures form coordination complexes with transition-metal ions, act as fullerene receptors and host small molecules in a crystal. Twit Text FOAVip Supramolecular macrocycles reversibly assembled by Te O chalcogen bonding ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=27090355 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=27090355 #FOAvip English Wikipedia <ref>{{Cite pmid|27090355}}</ref> Supramolecular macrocycles reversibly assembled by Te?O chalcogen bonding #MMPMID27090355 Ho PC; Szydlowski P; Sinclair J; Elder PJW; Kübel J; Gendy C; Lee LM; Jenkins H; Britten JF; Morim DR; Vargas-Baca I Nat Commun 2016[]; 7 (ä): ä PMID27090355show ga Organic molecules with heavy main-group elements frequently form supramolecular links to electron-rich centres. One particular case of such interactions is halogen bonding. Most studies of this phenomenon have been concerned with either dimers or infinitely extended structures (polymers and lattices) but well-defined cyclic structures remain elusive. Here we present oligomeric aggregates of heterocycles that are linked by chalcogen-centered interactions and behave as genuine macrocyclic species. The molecules of 3-methyl-5-phenyl-1,2-tellurazole 2-oxide assemble a variety of supramolecular aggregates that includes cyclic tetramers and hexamers, as well as a helical polymer. In all these aggregates, the building blocks are connected by Te?O?N bridges. Nuclear magnetic resonance spectroscopic experiments demonstrate that the two types of annular aggregates are persistent in solution. These self-assembled structures form coordination complexes with transition-metal ions, act as fullerene receptors and host small molecules in a crystal. äSupramolecular macrocycles reversibly assembled by Te?O chalcogen bond(epmc).pdf DeepDyve Pubget Overpricing