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10.1002/cphc.201501075 http://scihub22266oqcxt.onion/10.1002/cphc.201501075 C4797363!4797363!26632426     free     free     free Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Chemphyschem 2016 ; 17 (2): 221-4 Nephropedia Template TP {{tp|p=26632426|t=2016. Excited?State Dynamics of a Two?Photon?Activatable Ruthenium Prodrug |pdf=|usr=}}{{26632426}} gab.com Text Excited State Dynamics of a Two Photon Activatable Ruthenium Prodrug JO: Chemphyschem http://www.kidney.de/pget.php?&tw=1&pmid=26632426 #FOAvip We present a new approach to investigate how the photodynamics of an octahedral ruthenium(II) complex activated through two?photon absorption (TPA) differ from the equivalent complex activated through one?photon absorption (OPA). We photoactivated a RuII polypyridyl complex containing bioactive monodentate ligands in the photodynamic therapy window (620?1000?nm) by using TPA and used transient UV/Vis absorption spectroscopy to elucidate its reaction pathways. Density functional calculations allowed us to identify the nature of the initially populated states and kinetic analysis recovers a photoactivation lifetime of approximately 100?ps. The dynamics displayed following TPA or OPA are identical, showing that TPA prodrug design may use knowledge gathered from the more numerous and easily conducted OPA studies. Twit Text FOAVip Excited State Dynamics of a Two Photon Activatable Ruthenium Prodrug ????Chemphyschem http://www.kidney.de/pget.php?&tw=1&pmid=26632426 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=26632426 #FOAvip English Wikipedia <ref>{{Cite pmid|26632426}}</ref> Excited?State Dynamics of a Two?Photon?Activatable Ruthenium Prodrug #MMPMID26632426 Greenough SE; Horbury MD; Smith NA; Sadler PJ; Paterson MJ; Stavros VG Chemphyschem 2016[Jan]; 17 (2): 221-4 PMID26632426show ga We present a new approach to investigate how the photodynamics of an octahedral ruthenium(II) complex activated through two?photon absorption (TPA) differ from the equivalent complex activated through one?photon absorption (OPA). We photoactivated a RuII polypyridyl complex containing bioactive monodentate ligands in the photodynamic therapy window (620?1000?nm) by using TPA and used transient UV/Vis absorption spectroscopy to elucidate its reaction pathways. Density functional calculations allowed us to identify the nature of the initially populated states and kinetic analysis recovers a photoactivation lifetime of approximately 100?ps. The dynamics displayed following TPA or OPA are identical, showing that TPA prodrug design may use knowledge gathered from the more numerous and easily conducted OPA studies. äExcited?State Dynamics of a Two?Photon?Activatable Ruthenium Prodrug (epmc).pdf DeepDyve Pubget Overpricing