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10.1016/j.ultramic.2015.12.004

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suck abstract from ncbi


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pmid26744830
      Ultramicroscopy 2016 ; 162 (ä): 52-60
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  • Oxidation-state sensitive imaging of cerium dioxide by atomic-resolution low-angle annular dark field scanning transmission electron microscopy #MMPMID26744830
  • Johnston-Peck AC ; Winterstein JP ; Roberts AD ; DuChene JS ; Qian K ; Sweeny BC ; Wei WD ; Sharma R ; Stach EA ; Herzing AA
  • Ultramicroscopy 2016[Mar]; 162 (ä): 52-60 PMID26744830 show ga
  • Low-angle annular dark field (LAADF) scanning transmission electron microscopy (STEM) imaging is presented as a method that is sensitive to the oxidation state of cerium ions in CeO2 nanoparticles. This relationship was validated through electron energy loss spectroscopy (EELS), in situ measurements, as well as multislice image simulations. Static displacements caused by the increased ionic radius of Ce(3+) influence the electron channeling process and increase electron scattering to low angles while reducing scatter to high angles. This process manifests itself by reducing the high-angle annular dark field (HAADF) signal intensity while increasing the LAADF signal intensity in close proximity to Ce(3+) ions. This technique can supplement STEM-EELS and in so doing, relax the experimental challenges associated with acquiring oxidation state information at high spatial resolutions.
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