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10.1038/ncomms10669 http://scihub22266oqcxt.onion/10.1038/ncomms10669 C4757791!4757791!26883278     free     free     free Deprecated: Implicit conversion from float 217.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 217.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 217.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 217.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 217.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 217.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 251.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 251.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Nat+Commun 2016 ; 7 (ä): ä Nephropedia Template TP {{tp|p=26883278|t=2016. Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets |pdf=|usr=}}{{26883278}} gab.com Text Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=26883278 #FOAvip Single-molecule magnets represent a promising route to achieve potential applications such as high-density information storage and spintronics devices. Among others, 4d/5d elements such as Re(IV) ion are found to exhibit very large magnetic anisotropy, and inclusion of this ion-aggregated clusters yields several attractive molecular magnets. Here, using ab intio calculations, we unravel the source of giant magnetic anisotropy associated with the Re(IV) ions by studying a series of mononuclear Re(IV) six coordinate complexes. The low-lying doublet states are found to be responsible for large magnetic anisotropy and the sign of the axial zero-field splitting parameter (D) can be categorically predicted based on the position of the ligand coordination. Large transverse anisotropy along with large hyperfine interactions opens up multiple relaxation channels leading to a fast quantum tunnelling of the magnetization (QTM) process. Enhancing the Re-ligand covalency is found to significantly quench the QTM process. Twit Text FOAVip Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=26883278 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=26883278 #FOAvip English Wikipedia <ref>{{Cite pmid|26883278}}</ref> Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets #MMPMID26883278 Singh SK; Rajaraman G Nat Commun 2016[]; 7 (ä): ä PMID26883278show ga Single-molecule magnets represent a promising route to achieve potential applications such as high-density information storage and spintronics devices. Among others, 4d/5d elements such as Re(IV) ion are found to exhibit very large magnetic anisotropy, and inclusion of this ion-aggregated clusters yields several attractive molecular magnets. Here, using ab intio calculations, we unravel the source of giant magnetic anisotropy associated with the Re(IV) ions by studying a series of mononuclear Re(IV) six coordinate complexes. The low-lying doublet states are found to be responsible for large magnetic anisotropy and the sign of the axial zero-field splitting parameter (D) can be categorically predicted based on the position of the ligand coordination. Large transverse anisotropy along with large hyperfine interactions opens up multiple relaxation channels leading to a fast quantum tunnelling of the magnetization (QTM) process. Enhancing the Re-ligand covalency is found to significantly quench the QTM process. äDeciphering the origin of giant magnetic anisotropy and fast quantum t(epmc).pdf DeepDyve Pubget Overpricing