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10.1126/sciadv.1500988

http://scihub22266oqcxt.onion/10.1126/sciadv.1500988
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suck abstract from ncbi


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pmid26665175
      Sci+Adv 2015 ; 1 (11 ): e1500988
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  • From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties #MMPMID26665175
  • Byers CP ; Zhang H ; Swearer DF ; Yorulmaz M ; Hoener BS ; Huang D ; Hoggard A ; Chang WS ; Mulvaney P ; Ringe E ; Halas NJ ; Nordlander P ; Link S ; Landes CF
  • Sci Adv 2015[Dec]; 1 (11 ): e1500988 PMID26665175 show ga
  • The optical properties of metallic nanoparticles are highly sensitive to interparticle distance, giving rise to dramatic but frequently irreversible color changes. By electrochemical modification of individual nanoparticles and nanoparticle pairs, we induced equally dramatic, yet reversible, changes in their optical properties. We achieved plasmon tuning by oxidation-reduction chemistry of Ag-AgCl shells on the surfaces of both individual and strongly coupled Au nanoparticle pairs, resulting in extreme but reversible changes in scattering line shape. We demonstrated reversible formation of the charge transfer plasmon mode by switching between capacitive and conductive electronic coupling mechanisms. Dynamic single-particle spectroelectrochemistry also gave an insight into the reaction kinetics and evolution of the charge transfer plasmon mode in an electrochemically tunable structure. Our study represents a highly useful approach to the precise tuning of the morphology of narrow interparticle gaps and will be of value for controlling and activating a range of properties such as extreme plasmon modulation, nanoscopic plasmon switching, and subnanometer tunable gap applications.
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