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10.1039/C5SC01912E

http://scihub22266oqcxt.onion/10.1039/C5SC01912E
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C4603534!4603534 !26478803
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suck abstract from ncbi


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pmid26478803
      Chem+Sci 2015 ; 6 (11 ): 6320-6324
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  • One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent #MMPMID26478803
  • Luo HY ; Michaelis VK ; Hodges S ; Griffin RG ; Román-Leshkov Y
  • Chem Sci 2015[Nov]; 6 (11 ): 6320-6324 PMID26478803 show ga
  • A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is synthesized in one-pot using a rationally designed organic structure-directing agent (OSDA). The OSDA is comprised of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m(2)g(-1), and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. Compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel-Crafts alkylation of benzene with benzyl alcohol.
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