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10.1038/ncomms9394

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suck abstract from ncbi


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pmid26403619
      Nat+Commun 2015 ; 6 (ä): 8394
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  • Macroscopic and high-throughput printing of aligned nanostructured polymer semiconductors for MHz large-area electronics #MMPMID26403619
  • Bucella SG ; Luzio A ; Gann E ; Thomsen L ; McNeill CR ; Pace G ; Perinot A ; Chen Z ; Facchetti A ; Caironi M
  • Nat Commun 2015[Sep]; 6 (ä): 8394 PMID26403619 show ga
  • High-mobility semiconducting polymers offer the opportunity to develop flexible and large-area electronics for several applications, including wearable, portable and distributed sensors, monitoring and actuating devices. An enabler of this technology is a scalable printing process achieving uniform electrical performances over large area. As opposed to the deposition of highly crystalline films, orientational alignment of polymer chains, albeit commonly achieved by non-scalable/slow bulk alignment schemes, is a more robust approach towards large-area electronics. By combining pre-aggregating solvents for formulating the semiconductor and by adopting a room temperature wired bar-coating technique, here we demonstrate the fast deposition of submonolayers and nanostructured films of a model electron-transporting polymer. Our approach enables directional self-assembling of polymer chains exhibiting large transport anisotropy and a mobility up to 6.4 cm(2) V(-1) s(-1), allowing very simple device architectures to operate at 3.3 MHz. Thus, the proposed deposition strategy is exceptionally promising for mass manufacturing of high-performance polymer circuits.
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