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10.1038/srep14555

http://scihub22266oqcxt.onion/10.1038/srep14555
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suck abstract from ncbi


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pmid26412693
      Sci+Rep 2015 ; 5 (ä): 14555
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  • Competition between diagonal and off-diagonal coupling gives rise to charge-transfer states in polymeric solar cells #MMPMID26412693
  • Yao Y ; Zhou N ; Prior J ; Zhao Y
  • Sci Rep 2015[Sep]; 5 (ä): 14555 PMID26412693 show ga
  • It has long been a puzzle on what drives charge separation in artificial polymeric solar cells as a consensus has yet to emerge among rivaling theories based upon electronic localization and delocalization pictures. Here we propose an alternative using the two-bath spin-boson model with simultaneous diagonal and off-diagonal coupling: the critical phase, which is born out of the competition of the two coupling types, and is neither localized nor delocalized. The decoherence-free feature of the critical phase also helps explain sustained coherence of the charge-transfer state. Exploiting Hamiltonian symmetries in an enhanced algorithm of density-matrix renormalization group, we map out boundaries of the critical phase to a precision previously unattainable, and determine the bath spectral densities inducive to the existence of the charge-transfer state.
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