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10.1016/j.sbsr.2015.06.003

http://scihub22266oqcxt.onion/10.1016/j.sbsr.2015.06.003
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C4566156!4566156!26380171
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suck abstract from ncbi


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pmid26380171      Sens+Biosensing+Res 2015 ; 5 (ä): 37-41
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  • MEISENHEIMER COMPLEX BETWEEN 2,4,6-TRINITROTOLUENE AND 3-AMINOPROPYLTRIETHOXYSILANE AND ITS USE FOR A PAPER-BASED SENSOR #MMPMID26380171
  • Hughes S; Dasary SSR; Begum S; Williams N; Yu H
  • Sens Biosensing Res 2015[Sep]; 5 (ä): 37-41 PMID26380171show ga
  • 2,4,6-Trinitrotoluene (TNT) forms a red-colored Meisenheimer complex with 3-aminopropyltrenthoxysilane (APTES) both in solution and on solid phase. The TNT-APTES complex is unique since it forms yellow-colored complexes with 2,4,6-trinitrophenol and 4-nitrophenol, and no complex with 2,4-dinitrotoluene. The absorption spectrum of TNT-APTES has two absorption bands at 530 and 650 nm, while APTES complexes with 2,4,6-trinitrophenol and 4-nitrophenol have absorption maxima at around 420 nm, and no absorption change for 2,4-dinitrotoluene. The TNT-APTES complex facilitates the exchange of the TNT-CH3 proton/deuteron with solvent molecules. The red color of TNT-APTES is immediately visible at 1 µM of TNT.
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