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10.1038/srep13913

http://scihub22266oqcxt.onion/10.1038/srep13913
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C4564805!4564805!26354713
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suck abstract from ncbi


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pmid26354713      Sci+Rep 2015 ; 5 (ä): ä
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  • Occurrence of chiral organochlorine compounds in the environmental matrices from King George Island and Ardley Island, west Antarctica #MMPMID26354713
  • Wang P; Zhang Q; Li Y; Zhu C; Chen Z; Zheng S; Sun H; Liang Y; Jiang G
  • Sci Rep 2015[]; 5 (ä): ä PMID26354713show ga
  • Chiral organochlorine compounds (OCs) were measured in various environmental matrices (air, soil and vegetation) from west Antarctica using high resolution gas chromatography coupled with high resolution mass spectrometry (HRGC/HRMS). They were generally detected at a global background level compared with the previous studies. ?-HCH and PCB-183 was observed in all the matrices except PCB-183 in two soil samples, while PCB-95, -136, -149, -174, -176 and o,p?-DDT were detected in most air but only a few solid matrices. Enantiomeric fractions (EFs) indicated that nonracemic residues of chiral OCs occurred in all the matrices and a wide variation of the EF values was observed in the vegetation. There was significant discrepancy between the EF values of PCB-183 and the racemic values, indicating that stereoselective depletion of PCB-183 was probably associated with the water-air exchange. The EFs values of ?-HCH were generally lower than the racemic values but no statistical difference was obtained in all the matrices except lichen, supporting the assumption that water-air exchange may make influence on long-range transport of ?-HCH.
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