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10.1038/srep13657

http://scihub22266oqcxt.onion/10.1038/srep13657
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suck abstract from ncbi


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pmid26338280
      Sci+Rep 2015 ; 5 (ä): 13657
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  • Insight into Evolution, Processing and Performance of Multi-length-scale Structures in Planar Heterojunction Perovskite Solar Cells #MMPMID26338280
  • Huang YC ; Tsao CS ; Cho YJ ; Chen KC ; Chiang KM ; Hsiao SY ; Chen CW ; Su CJ ; Jeng US ; Lin HW
  • Sci Rep 2015[Sep]; 5 (ä): 13657 PMID26338280 show ga
  • The structural characterization correlated to the processing control of hierarchical structure of planar heterojunction perovskite layer is still incomplete due to the limitations of conventional microscopy and X-ray diffraction. This present study performed the simultaneously grazing-incidence small-angle scattering and wide-angle scattering (GISAXS/GIWAXS) techniques to quantitatively probe the hierarchical structure of the planar heterojunction perovskite solar cells. The result is complementary to the currently microscopic study. Correlation between the crystallization behavior, crystal orientation, nano- and meso-scale internal structure and surface morphology of perovskite film as functions of various processing control parameters is reported for the first time. The structural transition from the fractal pore network to the surface fractal can be tuned by the chloride percentage. The GISAXS/GIWAXS measurement provides the comprehensive understanding of concurrent evolution of the film morphology and crystallization correlated to the high performance. The result can provide the insight into formation mechanism and rational synthesis design.
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