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10.1038/ncomms8471

http://scihub22266oqcxt.onion/10.1038/ncomms8471
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suck abstract from ncbi


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pmid26101051
      Nat+Commun 2015 ; 6 (ä): 7471
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  • Spatial and temporal imaging of long-range charge transport in perovskite thin films by ultrafast microscopy #MMPMID26101051
  • Guo Z ; Manser JS ; Wan Y ; Kamat PV ; Huang L
  • Nat Commun 2015[Jun]; 6 (ä): 7471 PMID26101051 show ga
  • Charge carrier diffusion coefficient and length are important physical parameters for semiconducting materials. Long-range carrier diffusion in perovskite thin films has led to remarkable solar cell efficiencies; however, spatial and temporal mechanisms of charge transport remain unclear. Here we present a direct measurement of carrier transport in space and in time by mapping carrier density with simultaneous ultrafast time resolution and ?50-nm spatial precision in perovskite thin films using transient absorption microscopy. These results directly visualize long-range carrier transport of ?220?nm in 2?ns for solution-processed polycrystalline CH3NH3PbI3 thin films. Variations of the carrier diffusion coefficient at the ?m length scale have been observed with values ranging between 0.05 and 0.08?cm(2)?s(-1). The spatially and temporally resolved measurements reported here underscore the importance of the local morphology and establish an important first step towards discerning the underlying transport properties of perovskite materials.
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